ISO INTERNATIONAL STANDARD 16000-14 First edition 2009-05-15 Indoor air . Part 14: Determination of total (gas and particle- phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Extraction, clean-up and analysis by high-resolution gas chromatography and mass spectrometry Airinterieur Partie 14: Dosage des polychlorobiphényles (PCB) de type dioxine et despolychlorodibenzo-p-dioxines(PCDD)/polychlorodibenzofuranes (PCDF) totaux (en phase gazeuse et en phase particulaire) - Extraction, purification et analyse par chromatographie en phase gazeuse haute résolution et spectrométrie de masse Reference number ISO 16000-14:2009(E) @ ISO 2009 Not for Resale ISO 16000-14:2009(E) PDF disclaimer This PDF file may contain embedded typefaces. In accordance with Adobe's licensing policy, this file may be printed or viewed but shall not be edited unless the typefaces which are embedded are licensed to and installed on the computer performing the editing. In accepts no liability in this area. Adobe is a trademark of Adobe Systems Incorporated. Details of the software products used to create this PDF file can be found in the General Info relative to the file; the PDF-creation parameters were optimized for printing. Every care has been taken to ensure that the file is suitable for use by IsO member bodies. In the unlikely event that a problem relating to it is found, please inform the Central Secretariat at the address given below COPYRIGHTPROTECTEDDOCUMENT @ ISO2009 All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means, IsO's member body in the country of the requester. ISO copyright office Case postale 56. CH-1211 Geneva 20 Tel. + 41 22 749 01 11 Fax + 41 22 749 09 47 E-mail [email protected] Web www.iso.org Published in Switzerland @ ISO 2009 - All rights reserved edwithoutlicense from IHS Not for Resale ISO 16000-14:2009(E) Contents Page Foreword. Introduction 1 Scope 2 Normative references 3 Terms, definitions and abbreviated terms 4 5 5 Apparatus and materials.. 6 Analysis .... 7 Minimum requirements for extraction and clean-up... 15 8 Identification and quantification ... 15 9 Quality assurance criteria for the procedure blanks 20 10 Recovery..... 21 11 Calculation and presentation of results .. 12 Safety measures .. 13 Performance characteristics .24 14 Interferences .... Annex A (informative) Structure, toxicity and calculation of toxic equivalents . Annex B (informative) Example for the clean-up of PCBs/PCDDs/PCDFs and the separation of PCBs from PCDDs/PCDFs... .. 32 Annex C (informative) Gc/MS analysis ... ... 36 Annex D (informative) Masses of the ions for PCDDs/PCDFs and PCBs. AnnexE(informative)Interferences.. AnnexF(normative)CalibrationsolutionsforGC/MScalibration Annex G (informative) Standard deviations, detection limits and indoor air concentrations for .. 50 Bibliography. 52 Copyrght International Organizaionforstandardizalonghts reserved ii se from IHS Not for Resale