论文标题
使用滞后区分触变,抗硫代疗法和粘弹性
Distinguishing thixotropy, anti-thixotropy, and viscoelasticity using hysteresis
论文作者
论文摘要
储层计算是预测湍流的有力工具,其简单的架构具有处理大型系统的计算效率。然而,其实现通常需要完整的状态向量测量和系统非线性知识。我们使用非线性投影函数将系统测量扩展到高维空间,然后将其输入到储层中以获得预测。我们展示了这种储层计算网络在时空混沌系统上的应用,该系统模拟了湍流的若干特征。我们表明,使用径向基函数作为非线性投影器,即使只有部分观测并且不知道控制方程,也能稳健地捕捉复杂的系统非线性。最后,我们表明,当测量稀疏、不完整且带有噪声,甚至控制方程变得不准确时,我们的网络仍然可以产生相当准确的预测,从而为实际湍流系统的无模型预测铺平了道路。
Thixotropy, anti-thixotropy, and viscoelasticity are three types of time-dependent dynamics that involve fundamentally different underlying physical processes. Yet distinguishing them can be very challenging, which hinders the understanding of structure-property relations. Here we show that hysteresis is a promising technique to contrast the three dynamics by exploring signatures of the most basic thixotropic, anti-thixotropic, and nonlinear viscoelastic models. From these signatures, using shear-rate controlled ramps that begin and end at high shear rates, we identify two distinguishing features in hysteresis loops. The first is the direction of the hysteresis loops: clockwise for thixotropy, but counterclockwise for viscoelasticity and anti-thixotropy. A second feature is achieved at high ramping rates where all responses lose hysteresis: the viscoelastic response shows a stress plateau at low shear rates (lack of stress relaxation), whereas the thixotropic and anti-thixotropic responses are purely viscous with minimal shear thinning or thickening. The features are observed independent of the model details. We establish further evidence for these signatures by experimentally measuring the hysteresis of thixotropic Laponite suspensions, anti-thixotropic carbon black suspensions, and viscoelastic poly (ethylene oxide) solutions. The protocols explored here can be used to distinguish thixotropy, anti-thixotropy, and viscoelasticity, which helps reveal the underlying microstructural physics of complex fluids.