论文标题

由非弹性电子隧道驱动的布朗分子电动机的动力学模型

A dynamical model for Brownian molecular motors driven by inelastic electron tunneling

论文作者

Ribetto, Federico D., Deghi, Sebastián E., Calvo, Hernán L., Bustos-Marún, Raúl A.

论文摘要

近年来,已经提出了由电流驱动和控制的几个人工分子电动机。与布朗机器类似,这些系统通过将随机的非弹性隧穿事件转变为分子的定向旋转来工作。尽管它们是未来分子机器的最终组成部分的重要性,但它们的建模尚未得到充分研究。在这里,我们开发了一个动态模型来描述这些系统。我们通过将模型应用于众所周知的分子运动来说明我们的模型的有效性和实用性,这表明所获得的结果与可用的实验数据一致。此外,我们演示了如何使用模型来提取一些难以访问的微观参数。最后,我们包括对电流诱导力(CIF)的预期影响的分析。我们的分析表明,尽管CIF的非保守贡献在某些情况下可能很重要,但在分析的情况下它们似乎并不重要。尽管如此,CIF的保守贡献可能足够强大,可以显着改变系统的动态。

In recent years, several artificial molecular motors driven and controlled by electric currents have been proposed. Similar to Brownian machines, these systems work by turning random inelastic tunneling events into a directional rotation of the molecule. Despite their importance as the ultimate component of future molecular machines, their modeling has not been sufficiently studied. Here, we develop a dynamical model to describe these systems. We illustrate the validity and usefulness of our model by applying it to a well-known molecular motor, showing that the obtained results are consistent with the available experimental data. Moreover, we demonstrate how to use our model to extract some difficult-to-access microscopic parameters. Finally, we include an analysis of the expected effects of current-induced forces (CIFs). Our analysis suggests that, although nonconservative contributions of the CIFs can be important in some scenarios, they do not seem important in the analyzed case. Despite this, the conservative contributions of CIFs could be strong enough to significantly alter the system's dynamics.

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