论文标题

沿壁的各向同性活性胶体的稳态推进

Steady state propulsion of isotropic active colloids along a wall

论文作者

Desai, Nikhil, Michelin, Sebastien

论文摘要

活跃的滴剂排放/吸收化学溶质,其浓度梯度会导致界面流动自身的运输和液滴推进。这种非线性耦合使主动降低能够达到定向的自我抛光,但如果对流液与降低溶质传输的比率(即PECLET数字PE)大于有限的临界阈值。在大多数实验情况下,活动滴无浮力,因此沿刚性表面游泳。然而,对其非线性运动的理论描述几乎完全集中在无界域上,以规避几何复杂性。为了克服这一差距,我们研究了沿着刚性壁的各向同性圆膜胶体推进的自发出现和非线性饱和,并被恒定的外力限制在其上(例如,重力)。在这里将这种流动粒子模型视为粘性活动滴的限制案例。我们表明,对于中等的PE,颗粒运动和相关的化学转运减少了化学引起的壁式排斥,从而导致粒子随着PE的增加而逐渐靠近壁。颗粒壁分离的这种减少并没有阻碍自我推测,伴随着壁诱导的溶质浓度梯度的有效重排,从而提高了其游泳速度。

Active drops emit/absorb chemical solutes, whose concentration gradients cause interfacial flows driving their own transport and the propulsion of the droplet. Such non-linear coupling enables active drops to achieve directed self-propulsion despite their isotropy, if the ratio of advective-to-diffusive solute transport, i.e. the Peclet number Pe, is larger than a finite critical threshold. In most experimental situations, active drops are non-neutrally buoyant and thus swim along rigid surfaces; yet theoretical descriptions of their non-linear motion focus almost exclusively on unbounded domains to circumvent geometric complexity. To overcome this gap in understanding, we investigate the spontaneous emergence and nonlinear saturation of propulsion of an isotropic phoretic colloid along a rigid wall, to which it is confined by a constant external force (e.g., gravity). This phoretic particle model is considered here as a limiting case for a viscous active drop. We show that, for moderate Pe, the particle motion and associated chemical transport reduce the chemically-induced wall repulsion, thereby causing the particle to swim progressively closer to the wall as Pe increases. Far from hindering self-propulsion, this reduction in the particle-wall separation is accompanied by a wall-induced efficient rearrangement of the solute concentration gradients driving the particle, thus augmenting its swimming speed.

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