论文标题

手性极化学:分析解决方案,直觉及其使用

Chiral Polaritonics: Analytic Solutions, Intuition and its Use

论文作者

Schäfer, Christian, Baranov, Denis G.

论文摘要

优先选择给定的对映异构体而不是手性对应物在下一个医疗药物设计时代的到来时越来越相关。同时,空腔量子电动力学已成长为一个坚实的框架,以控制能量转移和化学反应性。在这项工作中,我们为与手性腔相互作用的许多手性发射器的系统得出了分析解决方案 - 类似于广泛使用的塔维斯 - 卡明斯和量子光学量的Hopfield模型。我们能够估计手性偏光元学的区分强度,讨论可能的未来发展方向,令人兴奋的应用,例如阐明同Riledality,并提供急需的直觉,以促进崭新的手性偏光型领域。

Preferential selection of a given enantiomer over its chiral counterpart becomes increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical reactivity. In this work, we derive an analytical solution to a system of many chiral emitters interacting with a chiral cavity -- in analogy to the widely used Tavis-Cummings and Hopfield models of quantum optics. We are able to estimate the discriminating strength of chiral polaritonics, discuss possible future development directions, exciting applications such as elucidating homochirality, and deliver much needed intuition to foster the freshly flourishing field of chiral polaritonics.

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