论文标题

局部反转对称性在bismuthate高-T_C $超导体中

Local inversion-symmetry breaking in a bismuthate high-$T_c$ superconductor

论文作者

Griffitt, S., Spaić, M., Joe, J., Anderson, Z., Zhai, D., Krogstad, M. J., Osborn, R., Pelc, D., Greven, M.

论文摘要

掺杂的perovskite babio $ _3 $表现出34 K的最大超导过渡温度($ t_c $),是第一个要发现的高级高$ t_c $氧化物,但有关金属和超导状态的性质的关键性问题仍然没有分辨。尽管人们通常认为,二态的超导性是常规的S波类型,但配对机制仍在争论中,具有强烈的电子 - phonon耦合和二晶价价或键构成可能起作用的作用。在这里,我们使用漫射X射线散射和蒙特卡洛建模来研究Ba $ _ {1-X} $ K $ _x $ bio $ _3 $的本地结构。我们没有发现解决重大难题的长期或短距离不成比例的证据,因为不成比例和相关的极性效应可能与金属和超导状态无关。取而代之的是,我们发现破坏反转对称性的纳米级结构相关性,这对电子物理(包括配对机制)具有深远的影响。此外,这一出乎意料的发现确立了bismuthates属于具有隐藏的自旋轨道耦合的更广泛的材料类别,并且倾向于倒置倒置的位移。

The doped perovskite BaBiO$_3$ exhibits a maximum superconducting transition temperature ($T_c$) of 34 K and was the first high-$T_c$ oxide to be discovered, yet pivotal questions regarding the nature of both the metallic and superconducting states remain unresolved. Although it is generally thought that superconductivity in the bismuthates is of the conventional s-wave type, the pairing mechanism is still debated, with strong electron-phonon coupling and bismuth valence or bond disproportionation possibly playing a role. Here we use diffuse x-ray scattering and Monte Carlo modeling to study the local structure of Ba$_{1-x}$K$_x$BiO$_3$ across its insulator-metal boundary. We find no evidence for either long- or short-range disproportionation, which resolves a major conundrum, as disproportionation and the related polaronic effects are likely not relevant for the metallic and superconducting states. Instead, we uncover nanoscale structural correlations that break inversion symmetry, which has far-reaching implications for the electronic physics, including the pairing mechanism. This unexpected finding furthermore establishes that the bismuthates belong to the broader classes of materials with hidden spin-orbit coupling and a tendency towards inversion-breaking displacements.

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