论文标题
部分可观测时空混沌系统的无模型预测
Simple 4-segment thermal cycling pyroelectric measurement protocol for differentiating between ferroelectric and non-ferroelectric materials
论文作者
论文摘要
稀有地球的铬酸盐(recro $ _3 $)和锰虫(Remno $ _3 $),其中re = eu = eu,y,y,dy,ho,gd经常受到审查,以寻找室温磁电磁性多效性。但是,在某些测量值中,伪影和不良信号在确认铁电(FE)阶段时构成了严重的挑战,尤其是在提及pyroelectric电流测量技术方面。在这方面,我们提出了一种简单的修改方法,用于将其称为4段热循环方案的高电电流测量。该协议有助于将难以捉摸的不可逆的热刺激电流与Fe相中的自发性和可逆性相关的电流中分离出来。为了解释协议的工作原理,我们比较了两种假设材料的模拟响应。没有太空费用和仅具有太空费用的副材料。此外,我们在原型铁电材料甘氨酸磷酸盐的单个晶体中实验验证了这些新方案。该报告主要侧重于使用两种多晶材料(Hocro $ _3 $ and dyfe $ _ {0.5} $ mn $ _ {0.5} $ o $ $ _3 $的详细调查,使用拟议的协议,使用了两种多晶材料,hocro $ _3 $和dyfe $ _ {0.5} $ _3 $。我们对pyreelectric研究的精明和仔细的方法阐述了在温度范围内没有可逆的自发性极化,hocro $ _3 $和dyfe $ _ {0.5} $ mn $ _ {0.5} $ _ {0.5} $ _3 $ _3 $。
The rare-earth chromates (RECrO$_3$) and manganites (REMnO$_3$) where, RE = Eu, Y, Dy, Ho, Gd are constantly under scrutiny in search of room temperature magnetoelectric multiferroics. However, the artefacts and undesirable signal in some of the measurements pose a severe challenge in confirming the ferroelectric (FE) phase, especially in reference to pyroelectric current measurement technique. In this regard, we propose a simple modified approach to pyroelectric current measurement named as 4-segment thermal cycling protocol. This protocol assists in isolating the elusive, irreversible thermally stimulated current from the currents associated with spontaneous and reversible nature of the electric polarization in FE phase. In order to explain working principle of the protocol, we have compared simulated response of two hypothetical materials; an FE material free of space charges and a paraelectric material possessing only space charges. Further, we experimentally verify these new protocols in a single crystal of prototype ferroelectric material, Glycine Phosphite. This report primarily focuses on detailed investigation of ferroelectricity using the proposed protocol in two polycrystalline materials, HoCrO$_3$ and DyFe$_{0.5}$Mn$_{0.5}$O$_3$ where, the former has been reported to be multiferroic earlier. Our elaborative and careful approach to pyroelectric studies expound on the absence of reversible spontaneous electric polarization at temperature ranges tested in both, HoCrO$_3$ and DyFe$_{0.5}$Mn$_{0.5}$O$_3$.