论文标题

具有分层硅双磷化物中带有声子侧带的非常规激素状态

Unconventional Excitonic States with Phonon Sidebands in Layered Silicon Diphosphide

论文作者

Zhou, Ling, Huang, Junwei, Windgaetter, Lukas, Ong, Chin Shen, Zhao, Xiaoxu, Zhang, Caorong, Tang, Ming, Li, Zeya, Qiu, Caiyu, Latini, Simone, Lu, Yangfan, Wu, Di, Gou, Huiyang, Wee, Andrew T. S., Hosono, Hideo, Louie, Steven G., Tang, Peizhe, Rubio, Angel, Yuan, Hongtao

论文摘要

准粒子(电子,激子和声子)之间的多体相互作用导致了新的复杂相关状态的出现,并且是凝结物质物理和材料科学的核心。在低维材料中,这些相关状态的独特电子性能可能会显着影响其光学特性。在此,我们结合了光致发光,光学反射测量和理论计算,我们证明了在分层二磷化硅(SIP $ _2 $)中的非常规激素状态及其结合的声子侧带,其中绑定的电子对由一个限制的电子对组成,并在磷酸化磷酸化的一维磷酸化中,并构成磷酸化的磷酸化。 sip $ _2 $层。激子状态和新兴的声子边带显示了线性二科运动和温度升高的大型能量红移。在$ GW $加上Bethe $ - $ SALPETER方程计算并非扰动地求解广义荷斯坦模型中,我们确认观察到的边带特征是由于激素与光学声子之间的相关相互作用而导致的。这样的分层材料为研究激发物理学和许多粒子效应提供了一个新的平台。

Many-body interactions between quasiparticles (electrons, excitons, and phonons) have led to the emergence of new complex correlated states and are at the core of condensed matter physics and material science. In low-dimensional materials, unique electronic properties for these correlated states could significantly affect their optical properties. Herein, combining photoluminescence, optical reflection measurements and theoretical calculations, we demonstrate an unconventional excitonic state and its bound phonon sideband in layered silicon diphosphide (SiP$_2$), in which the bound electron-hole pair is composed of electrons confined within one-dimensional phosphorus$-$phosphorus chains and holes extended in two-dimensional SiP$_2$ layers. The excitonic state and the emergent phonon sideband show linear dichroism and large energy redshifts with increasing temperature. Within the $GW$ plus Bethe$-$Salpeter equation calculations and solving the generalized Holstein model non-perturbatively, we confirm that the observed sideband feature results from the correlated interaction between excitons and optical phonons. Such a layered material provides a new platform to study excitonic physics and many-particle effects.

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