论文标题
与Herzberg-Teller振动耦合的非核对光谱的相关驾驶方程
Correlated driving-and-dissipation equation for non-Condon spectroscopy with the Herzberg-Teller vibronic coupling
论文作者
论文摘要
相关驾驶方程(CODDE)是一种优化的完整二阶量子耗散方法,最初仅与减少的系统动力学有关。但是,实际上可以借助于动作方程理论(一种统计准粒子量子耗散形式主义形式主义,可以从CODDE提取杂交浴动力学。被视为一种{dissipaton理论,Codde成功地扩展了以处理偶极场相互作用中的Herzberg-Teller振动耦合。示范将在模型二聚体系统的非传统光谱上进行。
Correlated driving-and-dissipation equation (CODDE) is an optimized complete second-order quantum dissipation approach, which is originally concerned with the reduced system dynamics only. However, one can actually extract the hybridized bath dynamics from CODDE with the aid of dissipaton-equation-of-motion theory, a statistical quasi-particle quantum dissipation formalism. Treated as an one{dissipaton theory, CODDE is successfully extended to deal with the Herzberg-Teller vibronic couplings in dipole-field interactions. Demonstrations will be carried out on the non-Condon spectroscopies of a model dimer system.