论文标题
热力学上一致的近似版本用于建模潮湿空气
Thermodynamically consistent versions of approximations used in modelling moist air
论文作者
论文摘要
建模潮湿空气热力学的一些现有方法使近似值破坏了$ \ textIt {热力学一致性} $,因此所得的热力学不会遵守第一和第二定律或其他不一致之处。最近,已经提出了一种避免这种不一致的方法:根据$ \ textit {自然变量} $的使用$ \ textit {热力学潜力} $,从中得出所有热力学数量和关系。在本文中,我们为$ \ textIt {未透明度} $潮湿的空气热力学和两个广泛使用的近似值开发了这种方法:常数$κ$近似值和干热能力近似。一致的常数$κ$近似特别有吸引力,因为当使用虚拟电势温度$θ_v$作为热力学变量时,仅取决于总质量,而与水形式之间的分解无关。此外,在大气建模中有关热力学文献中不同来源的各种材料都将其汇总在一起。希望本文为在大气建模中使用热力学潜力提供全面的参考,尤其是对于此处考虑的三个系统。
Some existing approaches to modeling the thermodynamics of moist air make approximations that break $\textit{thermodynamic consistency}$, such that the resulting thermodynamics do not obey the 1st and 2nd laws or have other inconsistencies. Recently, an approach to avoid such inconsistency has been suggested: the use of $\textit{thermodynamic potentials}$ in terms of their $\textit{natural variables}$, from which all thermodynamic quantities and relationships are derived. In this paper, we develop this approach for $\textit{unapproximated}$ moist air thermodynamics and two widely used approximations: the constant $κ$ approximation and the dry heat capacities approximation. The consistent constant $κ$ approximation is particularly attractive because it leads to, when using virtual potential temperature $θ_v$ as the thermodynamic variable, adiabatic dynamics that depend only on total mass, independent of the breakdown between water forms. Additionally, a wide variety of material from different sources in the literature on thermodynamics in atmospheric modelling is brought together. It is hoped that this paper provides a comprehensive reference for the use of thermodynamic potentials in atmospheric modelling, especially for the three systems considered here.