论文标题

应力诱导的ZRSIO4声子频率的变化是否可以使其成为基于IR光谱的潜在压力传感器?

Can stress-induced changes in phonon frequencies of ZrSiO4 make it a potential IR spectroscopy-based pressure sensor?

论文作者

Mansoor, Mubashir, Mansoor, Mehya, Mansoor, Maryam, Er, Zuhal, Czelej, Kamil, Urgen, Mustafa

论文摘要

可以用作高压传感器的功能材料受到限制,从而使人们受到追捧。据报道,静水压力极大地影响了ZRSIO4的拉曼偏移。因此,已建议硅酸锆为拉曼光谱压力传感器。但是,基于拉曼的传感器技术的大规模应用构成了广泛的挑战。我们证明ZRSIO4还表现出压力依赖性红外(IR)光谱。此外,ZRSIO4的IR峰对剪切应力和非静压压力敏感,使该材料成为通过IR光谱确定各种机械应力的独特传感器。

Functional materials that can serve as high-pressure transducers are limited, making such sensor material sought after. It has been reported that hydrostatic pressures highly influence Raman shifts of ZrSiO4. Therefore, zirconium silicate has been suggested as a Raman spectroscopic pressure sensor. However, mass applications of a Raman-based sensor technology poses a wide range of challenges. We demonstrate that ZrSiO4 also exhibits pressure-dependent infrared (IR) spectra. Furthermore, the IR peaks of ZrSiO4 are sensitive to shear stresses and non-hydrostatic pressures, making this material a unique sensor for determining a variety of mechanical stresses through IR spectroscopy.

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