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In future 6G millimeter wave (mmWave)/sub-THz vehicle-to-everything (V2X) communication systems, vehicles are expected to be equipped with massive antenna arrays to realize beam-based links capable of compensating for the severe path loss. However, vehicle-to-vehicle (V2V) direct links are prone to be blocked by surrounding vehicles. Emerging metasurface technologies enable the control of the electromagnetic wave reflection towards the desired direction, enriching the channel scattering to boost communication performance. Reconfigurable intelligent surfaces (RIS), and mostly the pre-configured counterpart intelligent reflecting surfaces (IRS), are a promising low-cost relaying system for 6G. This paper proposes using conformal metasurfaces (either C-RIS or C-IRS) deployed on vehicles' body to mitigate the blockage impact in a highway multi-lane scenario. In particular, conformal metasurfaces create artificial reflections to mitigate blockage by compensating for the non-flat shape of the vehicle's body, such as the lateral doors, with proper phase patterns. We analytically derive the phase pattern to apply to a cylindrical C-RIS/C-IRS approximating the shape of the car body, as a function of both incidence and reflection angles, considering cylindrical RIS/IRS as a generalization of conventional planar ones. We propose a novel design for optimally pre-configured C-IRS to mimic the behavior of an EM flat surface on car doors, proving the benefits of C-RIS and C-IRS in a multi-lane V2V highway scenario. The results show a consistent reduction of blockage probability when exploiting C-RIS/C-IRS, 20% for pre-configured C-IRS, and 70% for C-RIS, as well as a remarkable improvement in terms of average signal-to-noise ratio, respectively 10-20 dB for C-IRS and 30-40 dB for C-RIS.