论文标题
低质量恒星形成区域中的连续申请:d $ _ {2} $ - 甲醇(chd $ _ {2} $ OH)的情况16293-2422
Successive deuteration in low-mass star-forming regions: the case of D$_{2}$-methanol (CHD$_{2}$OH) in IRAS 16293-2422
论文作者
论文摘要
在深层嵌入的低质量原子系统和星体化学模板源IRAS16293-2422中,二二酸甲醇的柱密度的准确定量是di二磷酸甲醇的柱密度。用于天体物理目的的光谱数据集是为CHD $ _ {2} $ oh构建的,并公开可用以促进该物种在星体化学调查中的准确表征。新计算的行列表和分区功能用于搜索CHD $ _ {2} $ OH,to IRAS16293-2422 A和B中的Alma-Pils数据中的数据。仅使用非混合,光学上的薄型$ _ {2} $ oh的线,用于合成光谱拟合。构造的光谱数据库包含在0到500 GHz频率范围内7417个过渡的线频率和强度。 329-363 GHz范围内的Alma-PILS观测值用于识别105个独特的,非混合的,光学上的细线频率$ _ {2} $ OH用于合成光谱拟合。派生的激发温度和色谱柱密度分别产生高d/h比的高d/h比$ _ {2} $ oh,在IRAS 16293-2422 A和B的7.5 $ \ pm $ \ pm $ 1.1%和7.7 $ \ pm $ 1.2%。 IRAS 16293-2422中的侵占不高于其他低质量恒星形成区域。在所有低质量质体中,二磷酸分子的D/H比始终高于其单调的对应物,这可能是H-D取代反应的自然结果,如实验室实验所示。太阳系的出生云由彗星67p/churyumov-gerasimenko所追踪,可能比IRAS16293-2422的云更温暖D的初始丰度,或者部分被重新处理。结合准确的光谱,仔细的光谱分析以及对基本假设的考虑,连续的剥离是恒星形成系统物理化学出处的强大窗口。
Accurate quantification of the column density of di-deuterated methanol is a key missing puzzle piece in the otherwise thoroughly constrained family of D-bearing methanol in the deeply embedded low-mass protostellar system and astrochemical template source IRAS16293-2422. A spectroscopic dataset for astrophysical purposes is built for CHD$_{2}$OH and made publicly available to facilitate accurate characterization of this species in astrochemical surveys. The newly computed line list and partition function are used to search for CHD$_{2}$OH towards IRAS16293-2422 A and B in data from ALMA-PILS. Only non-blended, optically thin lines of CHD$_{2}$OH are used for the synthetic spectral fitting. The constructed spectroscopic database contains line frequencies and strengths for 7417 transitions in the 0 to 500 GHz frequency range. ALMA-PILS observations in the 329-363 GHz range are used to identify 105 unique, non-blended, optically thin line frequencies of CHD$_{2}$OH for synthetic spectral fitting. The derived excitation temperatures and column densities yield high D/H ratios of CHD$_{2}$OH in IRAS 16293-2422 A and B of 7.5$\pm$1.1% and 7.7$\pm$1.2%, respectively. Deuteration in IRAS 16293-2422 is not higher than in other low-mass star-forming regions. Di-deuterated molecules consistently have higher D/H ratios than their monodeuterated counterparts in all low-mass protostars, which may be a natural consequence of H-D substitution reactions as seen in laboratory experiments. The Solar System's natal cloud, as traced by comet 67P/Churyumov-Gerasimenko, may have had a lower initial abundance of D, been warmer than the cloud of IRAS16293-2422, or been partially reprocessed. In combination with accurate spectroscopy, a careful spectral analysis, and a consideration of the underlying assumptions, successive deuteration is a robust window on the physicochemical provenance of star-forming systems.