论文标题
胶体悬浮液的凝胶化的声学监测
Acoustic monitoring of the gelation of a colloidal suspension
论文作者
论文摘要
由于它们对材料的机械性能敏感,并且即使在不透明的系统中也可以传播,因此声波为我们提供了许多领域中强大的表征工具。通用技术主要依赖于飞行时间的测量,并且不利用光谱内容:但是,音速和衰减光谱包含丰富的信息。这样的声学光谱已经存在,并允许检索有关众所周知的物理化学系统的微妙信息,但是对于工业系统而言,建模变得遥不可及。在本文中,我们使用一种简单的经验方法来监测二氧化硅悬浮液的凝胶:我们表明,从声学测量中获得的凝胶时间与更常规的流变学表征成正比。因此,这样的结果为仅使用声学方法的工业环境中时间不断发展的系统的原位监视开辟了道路。
Because they are sensitive to mechanical properties of materials and can propagate even in opaque systems, acoustic waves provides us with a powerful characterization tool in numerous fields. Common techniques mostly rely on time-of-flight measurements and do not exploit the spectral content: however, sound speed and attenuation spectra contain rich information. Such an acoustic spectroscopy already exists and allows to retrieve subtle information on systems of well-known physico-chemistry, but modeling becomes out of reach for industrial systems. In this article, we use a simple empirical approach to monitor the gelation of silica suspensions: we show that the gelation time obtained from acoustic measurements is proportional to this determined with more conventional rheological characterization. Such a results thus opens the way for in-situ monitoring of time-evolving systems in industrial context with acoustic methods only.