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In generic curved spacetimes, the unavailability of a natural choice of vacuum state introduces a serious ambiguity in the Fock quantization of fields. In this review, we study the case of fermions described by a Dirac field in several cosmological spacetimes, and present recent results about well-motivated criteria that ensure the uniqueness in the selection of a vacuum up to unitary transformations. These criteria are based on two requirements. First, the invariance of the vacuum under the symmetries of the Dirac equations in the considered spacetime. Second, the unitary implementability of the Heisenberg dynamics of the annihilation and creation operators when the curved spacetime is treated as a fixed background. This last requirement not only permits the uniqueness of the Fock quantization but, remarkably, it also determines an essentially unique splitting between the phase space variables assigned to the background and the fermionic annihilation and creation variables. We first consider Dirac fields in cosmological spacetimes of 2+1 dimensions and then discuss the more relevant case of 3+1 dimensions. We use this analysis to investigate the hybrid loop quantization of a flat Friedmann-Lemaître-Robertson-Walker background cosmology coupled to a perturbative Dirac field. Among the Fock quantizations for the fermionic perturbations allowed by our criteria, we further restrict the choice of vacuum by demanding a finite fermionic backreaction and, moreover, by diagonalizing the fermionic contribution to the total Hamiltonian in the asymptotic limit of large wave numbers of the Dirac modes. Finally, we argue in support of the uniquess of the vacuum state selected by the extension of this diagonalization condition beyond the ultraviolet regime, proving that it picks out the standard Poincaré and Bunch-Davies vacua for fixed flat and de Sitter background spacetimes, respectively.