论文标题
拉普拉斯框架中的化学反应网络
Chemical Reaction Networks in a Laplacian Framework
论文作者
论文摘要
对化学反应的动力学的研究,尤其是振荡反应的现象,导致人们认识到,可以从某个有向图的图理论特性(称为化学反应网络(CRN))的图理论特性来预测化学反应的许多动力学特性。在此图中,边缘表示化学物质的反应和顶点。 与经典的处理相反,在这项工作中,我们严重依靠最近开发的定向图拉普拉斯人的理论来简化所谓的CRN理论零系统的传统处理。我们表明,可以通过分析与系统相关的有向图拉普拉斯元素来理解这些微分方程的多项式系统的许多动力学。除了更简洁的数学处理外,这还导致了更强的结果。特别是(i)我们表明,我们的拉普拉斯缺乏率零定理比传统的定理明显强,并且(ii)我们在所有(laplacian)缺陷的情况下得出了平衡基因座的简单方程。 本文以一种方式编写,以使数学受众易于访问材料。特别是,不假定对化学或物理学的了解。
The study of the dynamics of chemical reactions, and in particular phenomena such as oscillating reactions, has led to the recognition that many dynamical properties of a chemical reaction can be predicted from graph theoretical properties of a certain directed graph, called a Chemical Reaction Network (CRN). In this graph, the edges represent the reactions and the vertices the reacting combinations of chemical substances. In contrast with the classical treatment, in this work, we heavily rely on a recently developed theory of directed graph Laplacians to simplify the traditional treatment of the so-called deficiency zero systems of CRN theory. We show that much of the dynamics of these polynomial systems of differential equations can be understood by analyzing the directed graph Laplacian associated with the system. Beside the more concise mathematical treatment, this leads to considerably stronger results. In particular, (i) we show that our Laplacian deficiency zero theorem is markedly stronger than the traditional one and (ii) we derive simple equations for the locus of the equilibria in all (Laplacian) deficiency zero cases. This paper is written in a way to make the material easily accessible to a mathematical audience. In particular, no knowledge of chemistry or physics is assumed.