论文标题
系外行星气氛中CH4,CO2和H2O的共存
Coexistence of CH4, CO2 and H2O in exoplanet atmospheres
论文作者
论文摘要
我们提出了基于H,C,O,N元素丰度低于约600 K的H,C,O,N元素丰度的分类。对于H,C,N,O的所有组合,都会运行化学平衡模型,并且发现了三种类型的溶液,这些溶液在温度,压力,压力和硝酸含量的变化方面都具有良好的良好性。 A键入大气中包含H2O,CH4,NH3和H2或N2,但只有CO2和O2的痕迹。 B型大气包含O2,H2O,CO2和N2,但仅CH4,NH3和H2的痕迹。 C型大气中包含H2O,CO2,CH4和N2,但仅痕迹NH3,H2和O2。其他分子仅在PPB或PPM浓度中存在于化学平衡中,具体取决于温度。在太阳系中找不到C型气氛,那里的气氛通常足够冷以使水凝结,但是系植物可能会容纳这种气氛。我们的模型表明,除水云外,还可以在C型大气中发生石墨(烟灰)云,这些云可能会在所有类型的大气中发生。完整的平衡冷凝模型表明,温暖岩石的吹气自然可以提供C型气氛。我们得出的结论是,如果存在C型大气,则在考虑CH4和CO2的共存时,会导致对系外行星中生物签名的假阳性检测,并建议其他更强大的非平衡标记。
We propose a classification of exoplanet atmospheres based on their H, C, O, N element abundances below about 600 K. Chemical equilibrium models were run for all combinations of H, C, N, O abundances, and three types of solutions were found, which are robust against variations of temperature, pressure and nitrogen abundance. Type A atmospheres contain H2O, CH4, NH3 and either H2 or N2, but only traces of CO2 and O2. Type B atmospheres contain O2, H2O, CO2 and N2, but only traces of CH4, NH3 and H2. Type C atmospheres contain H2O, CO2, CH4 and N2, but only traces of NH3, H2 and O2. Other molecules are only present in ppb or ppm concentrations in chemical equilibrium, depending on temperature. Type C atmospheres are not found in the solar system, where atmospheres are generally cold enough for water to condense, but exoplanets may well host such atmospheres. Our models show that graphite (soot) clouds can occur in type C atmospheres in addition to water clouds, which can occur in all types of atmospheres. Full equilibrium condensation models show that the outgassing from warm rock can naturally provide type C atmospheres. We conclude that type C atmospheres, if they exist, would lead to false positive detections of biosignatures in exoplanets when considering the coexistence of CH4 and CO2, and suggest other, more robust non-equilibrium markers.