论文标题
由于光引起的结构扭曲
Chiral charge-density wave in TiSe$_2$ due to photo-induced structural distortions
论文作者
论文摘要
已经进行了各种实验,以建立1tise $ _2 $中手性电荷波过渡的起源,这又导致了关于此过渡起源的矛盾结论。一些研究表明,过渡是一种由声子驱动的结构失真,而其他研究表明,这是一种激子绝缘体相变,伴随着晶格失真。首先,如果一个人在正式的定义中分析了构成激子绝缘子的正式定义中的可用实验和理论数据,则可以对这些解释进行核对。接下来,我们介绍圆形极化光学转换和第一原理计算的泵探针测量值,其中我们强调了结构扭曲的重要性,以解释CDW阶段光学转变的有限手性。我们表明,在光激发时发生的电子温度升高时,存在一种非中心对称结构,其能量几乎是粒子电荷密度波结构,该结构解释了在Tise $ _2 $的CDW相中观察到的光学转变的有限手性。
A variety of experiments have been carried out to establish the origin of the chiral charge-density wave transition in 1T-TiSe$_2$, which in turn has led to contradictory conclusions on the origin of this transition. Some studies suggest the transition is a phonon-driven structural distortion while other studies suggest it is an excitonic insulator phase transition that is accompanied by a lattice distortion. First, we propose these interpretations can be reconciled if one analyzes the available experimental and theoretical data within a formal definition of what constitutes an excitonic insulator as initially proposed by Keldysh and Kopaev. Next, we present pump-probe measurements of circularly polarized optical transitions and first-principles calculations where we highlight the importance of accounting for structural distortions to explain the finite chirality of optical transitions in the CDW phase. We show that at the elevated electronic temperature that occurs upon photoexcitation, there is a non-centrosymmetric structure that is near-degenerate in energy with the centrosymmetric charge density wave structure, which explains the finite chirality of the optical transitions observed in the CDW phase of TiSe$_2$.