论文标题

星际尘埃中的有机物在进入地球层的方法时失去了:太阳点燃的自由基的放热化学反应

Organic matter in interstellar dust lost at the approach to the heliosphere: Exothermic chemical reactions of free radicals ignited by the Sun

论文作者

Kimura, Hiroshi, Postberg, Frank, Altobelli, Nicolas, Trieloff, Mario

论文摘要

目标。当在太阳系内测量时,我们解决了星际灰尘中缺少的有机材料的难题,而无疑存在于周围太阳系的当地星际云(LIC)中。 方法。我们提出了一个理论上的论点,即当太阳能日期触发自由基的重组或化合物中碳键的重排时,有机几乎通过放热反应即时升华。 结果。事实证明,通过考虑有机材料的升华发生在星际中性原子的所谓过滤区域之外,触发温度在20 $ -50 K的范围内。我们发现,除非考虑到有机材料的升华,否则太阳系中LIC尘埃的原位测量会导致LIC的气体与盘状质量比高估。我们还发现,先前对星际拾音器离子的测量已经确定了气体和有机材料的总元素丰度,而不是单独的星际气体。 结论。我们得出的结论是,LIT有机物在通往地球层的途径中遭受了升华,这意味着我们对太空任务中的LIC粉尘的理解是不完整的。由于土星轨道内部的太空任务无法提供有关LIC DUST的有机物质的任何信息,因此必须等待未来的勘探任务,以透露到Oort云的内部边缘,以彻底了解LIC中的有机物质。一旦确认了自由基的放热化学反应来升华星际有机物的模型,就排除了弥漫性星际培养基中粉刷的假设。

Aims. We tackle the conundrums of organic materials missing from interstellar dust when measured inside the Solar System, while undoubtedly existing in the local interstellar cloud (LIC), which surrounds the Solar System. Methods. We present a theoretical argument that organic compounds sublimate almost instantaneously by exothermic reactions, when solar insolation triggers the recombination of free radicals or the rearrangement of carbon bonds in the compounds. Results. It turns out that the triggering temperature lies in the range of 20$-$50 K by considering that sublimation of organic materials takes place beyond the so-called filtration region of interstellar neutral atoms. We find that in-situ measurements of LIC dust in the Solar System result in an overestimate for the gas-to-dust mass ratio of the LIC, unless the sublimation of organic materials is taken into account. We also find that previous measurements of interstellar pickup ions have determined the total elemental abundances of gas and organic materials, instead of interstellar gas alone. Conclusions. We conclude that LIC organic matter suffers from sublimation en route to the heliosphere, implying that our understanding of LIC dust from space missions is incomplete. Since space missions inside the orbit of Saturn cannot give any information on the organic substances of LIC dust, one must await a future exploration mission to the inner edge of the Oort cloud for a thorough understanding of organic substances in the LIC. Once our model for the sublimation of interstellar organic matter by exothermic chemical reactions of free radicals is confirmed, the hypothesis of panspermia from the diffuse interstellar medium is ruled out.

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