论文标题

精益稳定预混合h $ _2 $火焰中的重组区域

The recombination region in lean steady premixed H$_2$ flames

论文作者

Graña-Otero, José

论文摘要

h $ _2 $预处理的火焰是在一个漫长而尾随的区域中闻名的,在该区域中,未燃烧的h $ _2 $和超过燃油消耗层逐渐衰减到热力学平衡的超平衡浓度。在这里认为,这个重组区域是由洗牌反应的过早淬火引起的二阶效应,该反应抑制了第一个近似值中的衰减达到平衡。 详细研究了其结构和动力学,以捕获其特征长度尺度的较小但有限的反应速率,这足以使扩散传输可忽略不计,因此将上游反馈链路与主要火焰结构停止。它是等温的,可以通过中等倾斜的火焰来描述H $ _2 $作为唯一的自由度,这是由于几乎完全被淬火的散落反应所施加的强烈约束进化的巨大降低结果。 因此,H $ _2 $和激进的衰减速率是由HO $ _2 $动力学控制的对流传输与化学水槽之间的平衡所决定的,这在洗牌反应淬火后变为主导。从本质上讲,这是一个两步机制,其第一个限制步骤将O $ _2 $转换为Ho $ _2 $,而第二个则包括多个快速的,平行的路径,因为HO $ _2 $转换为O $ _2 $和H $ _2 $ o。 当不适用一种自由模型时,对非常瘦和几乎化学计量的火焰进行了概括,并且还简要讨论了热量损失的效果。

H$_2$ premixed flames are well known for a long, trailing region where the unburnt H$_2$ and the super-equilibrium concentrations of radicals left past the fuel consumption layer gradually decay to thermodynamic equilibrium. This recombination region, it's argued here, is a second order effect induced by the premature quenching of the shuffle reactions, which inhibits the decay to equilibrium in the first approximation. Its structure and kinetics are studied in detail to capture the small but finite reaction rates accounting for its characteristic length scale, which is large enough to render the diffusive transport negligible, hence deactivating the upstream feedback link with the main flame structure. It is isothermal and can be described, in moderately lean flames, by just the distribution of H$_2$ as the sole degree of freedom, a drastic reduction consequence of the strongly constrained evolution imposed by the almost exactly quenched shuffle reactions. The rate of decay to equilibrium of H$_2$ and radicals is thus dictated by the balance between the convective transport and chemical sinks controlled by the HO$_2$ kinetics, which becomes dominant after the shuffle reactions quench. Essentially, it is a two-step mechanism with the first, rate-limiting step converting O$_2$ into HO$_2$, whereas the second one, comprising multiple fast, parallel pathways, depletes radicals as HO$_2$ is converted into O$_2$ and H$_2$O. Generalizations to very lean and nearly stoichiometric flames, when the one degree of freedom model is not applicable, as well as the effect of heat losses are also briefly discussed.

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