学术文献库

In this study, the synergistic effect of the particle size of the dispersed phase and the interface thermal resistance (R$_{int}$) between the phases on the phonon thermal conductivity ($κ_{ph}$) of the (1-x)La$_{0.95}$Sr$_{0.05}$Co$_{0.95}$Mn$_{0.05}$O$_3$/(x)WC thermoelectric composite, is demonstrated. Further, the correlation between the R$_{int}$ and the Kapitza radius is discussed using the Bruggeman's asymmetrical model. In particular, the polycrystalline La$_{0.95}$Sr$_{0.05}$Co$_{0.95}$Mn$_{0.05}$O$_3$ sample is synthesized using a standard-solid state route. The presence of WC nanoparticle is confirmed from the electron microscopy images. Electrical conductivity ($σ$) increases, and the Seebeck coefficient ($α$) decreases with the increase in conducting WC volume fraction in the composite. The simultaneous increase in $σ$ and a decrease in $κ_{ph}$ with the WC volume fraction results in an increased figure of merit (zT) for (1-x)La$_{0.95}$Sr$_{0.05}$Co$_{0.95}$Mn$_{0.05}$O$_3$/(x)WC composite. A maximum zT $\sim$ 0.20 is obtained for (1-x)La$_{0.95}$Sr$_{0.05}$Co$_{0.95}$Mn$_{0.05}$O$_3$/(x)WC composite for x=0.010 at 463 K. The results obtained in the present study shows promise to design thermoelectric composites with desired phonon thermal conductivity considering the elastic properties between the phases.