论文标题
复杂量子动力学的模型非依赖性模拟复杂性
Model-Independent Simulation Complexity of Complex Quantum Dynamics
论文作者
论文摘要
我们提出了一种基于模拟的动力学复杂性的模型量度,基于使用频闪仪的马尔可夫动力学模拟复杂的量子动力学。经典信号处理的工具使我们能够通过脉冲询问来推断在与时间无关的哈密顿量下演变的复杂量子系统的希尔伯特空间维度。我们为自旋 - 玻色子模型和模拟的三阶泵探针光谱数据评估了模型独立的模拟复杂性(MISC),以在具有振动水平的耦合二聚体中进行激子传输。前者提供了对两级系统中连贯性和人口动态的见解,而后者则揭示了二聚体的单一流形的维度。最后,我们使用来自两个最近的非线性超快光谱实验的数据中的数据探测了光收集2(LH2)和Fenna-Matthews-Olson(FMO)复合物中激素转运的复杂性。对于后者,我们进行了一些与模型特定的推论。这包括估计拟合实验数据并识别在此复杂量子动力学中发生的量子状态的空间范围,即定位大小所需的最少数量的参数。
We present a model-independent measure of dynamical complexity based on simulating complex quantum dynamics using stroboscopic Markovian dynamics. Tools from classical signal processing enable us to infer the Hilbert space dimension of a complex quantum system evolving under a time-independent Hamiltonian via pulsed interrogation. We evaluate our model-independent simulation complexity (MISC) for the spin-boson model and simulated third-order pump-probe spectroscopy data for exciton transport in coupled dimers with vibrational levels. The former provides insights into coherence and population dynamics in the two-level system while the latter reveals the dimension of the singly-excited manifold of the dimer. Finally, we probe the complexity of excitonic transport in light harvesting 2 (LH2) and Fenna-Matthews-Olson (FMO) complexes using data from two recent nonlinear ultrafast optical spectroscopy experiments. For the latter we make some model-independent inferences that are commensurate with model-specific ones. This includes estimating the fewest number of parameters needed to fit the experimental data and identifying the spatial extent, i.e., delocalization size, of quantum states occurring in this complex quantum dynamics.