论文标题

Ag隔离的刻度图在不对称Cu倾斜晶界处诱导纳米面

Faceting diagram for Ag segregation induced nanofaceting at an asymmetric Cu tilt grain boundary

论文作者

Peter, Nicolas J., Duarte, Maria J., Kirchlechner, Christoph, Liebscher, Christian H., Dehm, Gerhard

论文摘要

在这项工作中,我们使用扩散夫妇方法在Cu-Ag系统中的不对称倾斜晶界进行实验性建立等温纳米曲面的演化。我们研究了Ag溶质过量浓度的依赖性沿晶界沿晶界的纳米形成。最初的晶界将分离为不对称的Ag-Lean片段和富含Ag的对称段(210)段。增加AG的过量会导致富含Ag的小相段的长度增加,而不对称方面的长度保持恒定。由此,我们构建了从局部原子结构,整体倾斜度和Ag溶质过量的实验中得出的晶界纳米图。

In this work, we experimentally establish the isothermal nanofacet evolution at an asymmetric tilt grain boundary in the Cu-Ag system using a diffusion couple approach. We investigate the nanofacet formation along the grain boundary in dependence of the Ag solute excess concentration. The initial grain boundary dissociates into asymmetric Ag-lean segments and Ag-rich symmetric (210) segments. Increasing Ag excess leads to an increase in Ag-rich facet segment length, while the length of the asymmetric facets remains constant. From this, we construct a grain boundary nanofaceting diagram deduced from our experiments relating local atomic structure, overall inclination and Ag solute excess.

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