论文标题
四维振动光谱,用于在BN纳米管中声子分散的纳米级映射
Four-dimensional Vibrational Spectroscopy for Nanoscale Mapping of Phonon Dispersion in BN Nanotubes
论文作者
论文摘要
直接测量各个纳米结构中局部声子分散体可以极大地提高我们对它们的电气,热和机械性能的理解。然而,这种实验测量需要极高的检测灵敏度,并且空间,能量和动量分辨率相结合,因此难以捉摸。在这里,我们开发了基于单色扫描透射电子显微镜(STEM)的四维电子能量损耗光谱(4D-EELS)技术,并介绍了位置依赖性的声子分散剂测量中的单个硝酸硼纳米管(BNNTS)。我们的测量表明,多壁BNNT的展开的声子分散量接近六边形氮化物(H-BN)晶体,这表明层间耦合和弯曲的几何形状对声子分散没有实质性的影响。我们还发现,声音子对动量依赖性缺陷散射极为敏感,而光学声子则易感性得多。这项工作不仅为BNNT的振动特性提供了有用的见解,而且还展示了纳米级声子分散测量中开发的4D-EELS技术的巨大前景。
Direct measurement of local phonon dispersion in individual nanostructures can greatly advance our understanding of their electrical, thermal, and mechanical properties. However, such experimental measurements require extremely high detection sensitivity and combined spatial, energy and momentum resolutions, thus has been elusive. Here, we develop a four-dimensional electron energy loss spectroscopy (4D-EELS) technique based a monochromated scanning transmission electron microscope (STEM), and present the position-dependent phonon dispersion measurement in individual boron nitride nanotubes (BNNTs). Our measurement shows that the unfolded phonon dispersion of multi-walled BNNTs is close to hexagonal-boron nitride (h-BN) crystals, suggesting that interlayer coupling and curved geometry have no substantial impacts on phonon dispersion. We also find that the acoustic phonons are extremely sensitive to momentum-dependent defect scattering, while optical phonons are much less susceptible. This work not only provides useful insights into vibrational properties of BNNTs, but also demonstrates huge prospects of the developed 4D-EELS technique in nanoscale phonon dispersion measurements.