论文标题
在硬超过的一些二进制混合物中解散和四序
Demixing and tetratic ordering in some binary mixtures of hard superellipses
论文作者
论文摘要
我们使用缩放粒子理论来检查硬质超细胞的二进制混合物的流体相位行为。超ellipse是一个一般的二维凸对象,可以在给定纵横比以圆形和矩形形状之间进行调谐。我们发现,即使两种物种的宽高比均固定,粒子的形状也会强烈影响各向同性列和三阶段的稳定性。虽然可以使用缩放粒子理论排除各向同性各向同性的解散过渡,但一阶各向同性列和列明列的脱节过渡可以通过组件之间的强分离来稳定。据观察,在小矩形大椭圆形混合物中,固定趋势最强。有趣的是,可以在硬矩形和矩形的混合物中稳定在较低密度的四个阶,其中长矩形形成列前相,而正方形则以四阶为单位。
We examine the fluid phase behaviour of the binary mixture of hard superellipses using the scaled particle theory The superellipse is a general two dimensional convex object which can be tuned between circular and rectangular shapes continuously at a given aspect ratio. We find that the shape of the particle affects strongly the stability of isotropic nematic and tetratic phases even if the aspect ratios of both species are fixed. While the isotropic isotropic demixing transition can be ruled out using the scaled particle theory the first order isotropic nematic and the nematic nematic demixing transition can be stabilized with strong fractionation between the components. It is observed that the demixing tendency is strongest in small rectangle large ellipse mixtures. Interestingly, it is possible to stabilize the tetratic order at lower densities in the mixture of hard squares and rectangles where the long rectangles form nematic phase, while the squares stay in tetratic order.