论文标题
量子热力学上一致的本地主方程
Quantum thermodynamically consistent local master equations
论文作者
论文摘要
本地主方程是建模开放量子系统的广泛工具,尤其是在多体系统的背景下。但是,这些方程式被认为会导致热力学异常和违反热力学定律。相比之下,在这里,我们严格地证明本地主方程与热力学及其定律一致,而无需诉诸微观模型,如先前的工作中所做的那样。特别是,我们考虑了与多个浴室接触的量子系统,并确定对总能量,热电流和熵生产率的相关贡献。我们表明,当人们认为我们为热电流提供了适当的表达时,热力学的第二定律就会成立。我们通过使用像经典随机热力学一样将量子概率电流连接到量子概率电流的启发式论证来确认量子热电流的结果。我们最终使用结果来研究一组作为热器件运行的量子转子的热力学特性,并表明三个转子的合适设计可以用作吸收冰箱或热整流器。对于此处考虑的机器,我们还使用增强学习算法对系统参数进行了优化。
Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems. These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of thermodynamics. In contrast, here we rigorously prove that local master equations are consistent with thermodynamics and its laws without resorting to a microscopic model, as done in previous works. In particular, we consider a quantum system in contact with multiple baths and identify the relevant contributions to the total energy, heat currents and entropy production rate. We show that the second law of thermodynamics holds when one considers the proper expression we derive for the heat currents. We confirm the results for the quantum heat currents by using a heuristic argument that connects the quantum probability currents with the energy currents, using an analogous approach as in classical stochastic thermodynamics. We finally use our results to investigate the thermodynamic properties of a set of quantum rotors operating as thermal devices and show that a suitable design of three rotors can work as an absorption refrigerator or a thermal rectifier. For the machines considered here, we also perform an optimisation of the system parameters using an algorithm of reinforcement learning.