论文标题
真空紫外线光谱与空间相关的电冰的光谱:1氮和氧气富含氧气的keV电子照射
Vacuum ultraviolet photoabsorption spectroscopy of space-related ices: 1 keV electron irradiation of nitrogen- and oxygen-rich ices
论文作者
论文摘要
在太阳系中已检测到分子氧,氮和臭氧。预计它们还存在于星形区域内的冰粒披风中。模拟冰的能量加工(离子,光子和电子)的实验室实验对于解释和指导未来的天文观测至关重要。我们提供了通过富含氮和氧气的氮和氧气的Vuv摄影光谱数据,这些数据将有助于鉴定在太阳系和星际介质的冰粒地幔上观察到的吸收带和/或光谱斜率。我们提出了冷冻O2和N2的VUV光吸收光谱,两者的1:1混合物以及一组新的系统的纯氮氧化物。在1 KEV电子轰击冰样之前和之后,在22 K处获得光谱。然后将冰退火到更高的温度,以研究其热演化。此外,将傅立叶转换红外光谱作为分子合成的次级探针,以更好地识别发挥作用的物理和化学过程。我们的VUV数据表明,在电子辐照纯O2和N2 ICE后,我们的实验中观察到臭氧和叠氮化物自由基(N3)。 O2:N2 = 1:1冰混合物的能量加工导致臭氧与一系列氮氧化物的形成。纯和混合物中固体氮氧化物的电子照射会诱导新物种的形成,例如O2,N2和其他氮氧化物在初始冰中不存在。鉴于它们与各种天体物理环境的相关性,这里讨论了结果。最后,我们表明,固体NO2和水的VUV光谱可以再现Ecceladus,Dione和Rhea的冷表面的观察性VUV谱,强烈表明在冰雪卫星的表面上存在氮氧化物。
Molecular oxygen, nitrogen, and ozone have been detected in the Solar System. They are also expected to be present in ice-grain mantles within star-forming regions. Laboratory experiments that simulate energetic processing (ions, photons, and electrons) of ices are essential for interpreting and directing future astronomical observations. We provide VUV photoabsorption spectroscopic data of energetically processed nitrogen- and oxygen-rich ices that will help to identify absorption bands and/or spectral slopes observed on icy objects in the Solar System and on ice-grain mantles of the interstellar medium. We present VUV photoabsorption spectra of frozen O2 and N2, a 1:1 mixture of both, and a new systematic set of pure and mixed nitrogen oxide ices. Spectra were obtained at 22 K before and after 1 keV electron bombardment of the ice sample. Ices were then annealed to higher temperatures to study their thermal evolution. In addition, Fourier-transform infrared spectroscopy was used as a secondary probe of molecular synthesis to better identify the physical and chemical processes at play. Our VUV data show that ozone and the azide radical (N3) are observed in our experiments after electron irradiation of pure O2 and N2 ices, respectively. Energetic processing of an O2:N2 = 1:1 ice mixture leads to the formation of ozone along with a series of nitrogen oxides. The electron irradiation of solid nitrogen oxides, pure and in mixtures, induces the formation of new species such as O2, N2 , and other nitrogen oxides not present in the initial ice. Results are discussed here in light of their relevance to various astrophysical environments. Finally, we show that VUV spectra of solid NO2 and water can reproduce the observational VUV profile of the cold surface of Enceladus, Dione, and Rhea, strongly suggesting the presence of nitrogen oxides on the surface of the icy Saturn moons.