论文标题
病毒系数在化学反应中的作用
Role of virial coefficients in chemical reaction
论文作者
论文摘要
van't hoff方程将化学反应的平衡常数$ k $与温度$ t $相关。尽管Van't Hoff图($ \ ln k $ vs $ 1/t $)是线性的,但对于某些化学反应,它是非线性的。在这项工作中,我们将这种观察结果归因于病毒系数。
van't Hoff equation relates equilibrium constant $K$ of a chemical reaction to temperature $T$. Though the van't Hoff plot ($\ln K$ vs $1/T$) is linear, it is nonlinear for certain chemical reactions. In this work we attribute such observations to virial coefficients.