论文标题
解决方案中的无障碍电子松弛 - 两个状态模型，具有时间域中的精确分析溶液
Barrierless electronic relaxation in solution -- two state model with exact analytical solution in time domain
论文作者
论文摘要
我们提出了一种分析方法，用于解决时间域中溶液中电子松弛问题，该方法是由在两个耦合电位的影响下进行扩散的粒子建模的。假定这两个电势之间的耦合是由任意位置和强度的Dirac Delta函数表示的。 Smoluchowskii方程用于模型两个电势上的扩散运动。我们报告了时间域中生存概率的分析表达。这是时间域中首次得出分析解决方案，该方法可用于解决涉及其他电位的问题。
We propose an analytical method for solving the problem of electronic relaxation in solution in time domain, modelled by a particle undergoing diffusion under the influence of two coupled potentials. The coupling between the two potentials is assumed to be represented by a Dirac delta function of arbitrary position and strength. Smoluchowskii equation is used model the diffusion motion on both the potentials. We report an analytical expression for survival probability in time domain. This is the first time analytical solution in time domain is derived and this method can be used to solve problems involving other potentials.
