论文标题

不可压缩湍流中化学平衡附近的反应性标量的波动和相关性

Fluctuations and correlations of reactive scalars near chemical equilibrium in incompressible turbulence

论文作者

Wu, Wenwei, Calzavarini, Enrico, Schmitt, François G., Wang, Lipo

论文摘要

研究了在湍流环境中进行化学反应的物种的统计特性。我们专注于第二和更高阶的可逆多组分反应的情况,在接近随机大型反应物源维持的化学平衡状态下,而湍流则高度发育。在这样的状态下,化学反应之间存在竞争,这种化学反应倾向于倾倒反应物浓度波动并增强其相关强度和相反增加的湍流混合,从而增加了波动并消除了相对相关性。我们表明,可以根据标量泰勒微尺度构建的独特控制参数,damkhöler编号($da_θ$),反应物扩散率和反应速率表征了波动的功能依赖性和在各种条件下,即在改变反应顺序,雷诺德斯和schmidt数字的各种条件下的功能依赖性。较大的是这样的damkhöler数,与在相同条件下被动标量场的波动相比,标量波动越多,而相关性的相关性更大。超过$da_θ\ simeq \ mathcal {o}(10)$超过此行为的饱和度。我们为这种现象提供了一个分析预测,该预测与直接数值模拟结果非常吻合。

The statistical properties of species undergoing chemical reactions in a turbulent environment are studied. We focus on the case of reversible multi-component reactions of second and higher orders, in a condition close to chemical equilibrium sustained by random large-scale reactant sources, while the turbulent flow is highly developed. In such a state a competition exists between the chemical reaction that tends to dump reactant concentration fluctuations and enhance their correlation intensity and the turbulent mixing that on the contrary increases fluctuations and remove relative correlations. We show that a unique control parameter, the Damkhöler number ($Da_θ$) that can be constructed from the scalar Taylor micro-scale, the reactant diffusivity and the reaction rate characterises the functional dependence of fluctuations and correlations in a variety of conditions, i.e., at changing the reaction order, the Reynolds and the Schmidt numbers. The larger is such a Damkhöler number the more depleted are the scalar fluctuations as compared to the fluctuations of a passive scalar field in the same conditions, and vice-versa the more intense are the correlations. A saturation in this behaviour is observed beyond $Da_θ\simeq \mathcal{O}(10)$. We provide an analytical prediction for this phenomenon which is in excellent agreement with direct numerical simulation results.

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