论文标题
表面活性剂结晶对十二烷纳米乳液的聚集速率的影响。外相的粘度变化
Influence of surfactant crystallization on the aggregation rate of dodecane-in-water nanoemulsions. Changes in the viscosity of the external phase
论文作者
论文摘要
用7.5 mM十二烷基硫酸钠(SDS)稳定的纳米乳剂的十二烷 - 水(D/W)纳米乳液的聚集速率被评估超过500 mM NaCl。与六烷基水中(H/W)乳液一样,发现絮凝率显然随离子强度降低,与理论预测明显不同。由于事实证明许多粒子模拟非常耗时,因此在实现进一步评估之前,必须对实验参数有准确的了解。在这里,由于表面活性剂相行为引起的水溶液粘度的变化被认为是引用现象的可能原因。外部粘度对模拟结果的影响是使用给定盐浓度下的表面活性剂溶液的实际粘度与在没有盐的情况下的价值之间进行评估的。为此,以20至25°C的温度测量了0.5和7.5 mm SDS溶液的粘度在300 A A A 900 mm NaCl之间。得出的结论是,由于表面活性剂晶体的形成而导致的水粘度的增强大大降低了聚集速率。然而,这种下降似乎不足以证明在25 C下观察到的肯德基的减少是合理的。但是,值得注意的是,表面活性剂溶液温度的5度变化会导致肯德基的显着降低。此外,这里使用一组两粒子模拟来说明这种方法对粘度贡献进行评估的局限性。可以证实,这种方法仅方便研究相互作用潜力对聚合率的影响,因为它以前是Fuchs [1936]。
Rates of aggregation of dodecane-in-water (d/w) nanoemulsions stabilized with 7.5 mM sodium dodecylsulfate (SDS) are evaluated beyond 500 mM NaCl. As in the case of hexadecane-in-water (h/w) emulsions, it is found that flocculation rates apparently decrease with the ionic strength, departing appreciably from theoretical predictions. Since many-particle simulations proved to be very time consuming, an accurate knowledge of experimental parameters is necessary prior to the realization of further evaluations. Here, the change in the viscosity of the aqueous solution due to the surfactant phase behavior is considered as a possible cause of referred phenomenon. The influence of the external viscosity on the outcome of the simulations is appraised using a quotient between the actual viscosity of the surfactant solution at a given salt concentration and its value in the absence of salt. For that purpose, the viscosity of 0.5 and 7.5 mM SDS solutions was measured between 300 an 900 mM NaCl for temperatures of 20 and 25 °C. It is concluded that the augment of the aqueous viscosity due to the formation of surfactant crystals diminish significantly the aggregation rate. Yet this decline seems insufficient to justify the observed reduction of kFC at 25 C. Nevertheless, it is noteworthy that a 5-degree change in the temperature of the surfactant solution causes a remarkable decrease of kFC . Additionally, a set of two-particle simulations is used here to illustrate the limitations of this methodology for the appraisal of the viscosity contribution. It is confirmed that such approach is only convenient to study the effect of the interaction potential on the aggregation rate, as it was formerly conceived by Fuchs [1936].