论文标题

试管的随机作用:将路径概率连接到测量

Stochastic action for tubes: Connecting path probabilities to measurement

论文作者

Kappler, Julian, Adhikari, Ronojoy

论文摘要

扩散过程的轨迹是连续但不可差异的,每种轨迹都随着概率消失而发生。这引入了理论之间的差距,其中在许多情况下使用路径概率,而实验中只有概率非零的事件才能测量。在这里,我们通过考虑扩散轨迹保持在光滑路径周围的小但有限半径的管中的概率来弥合这一间隙。可以通过实验测量这种概率,该轨迹首次退出管子的速率,从而在路径概率和物理可观察物之间建立联系。考虑到$ n $维度过度抑制了Langevin动力学,我们表明可以从Fokker-Planck方程的解决方案中从理论上获得管概率。将所得的退出速率表示为路径的功能并将其订购为管半径中的功率序列,我们将零级术语确定为onsager-machlup随机动作,从而将其从数学构建体提升到物理可观察的。高阶术语首次揭示了有限拉迪乌斯贡献的形式,该形式解释了路径周围的波动。为了证明该动作功能与管子的实验相关性,我们以双孔电势进行数值对布朗运动的轨迹进行样品,计算其退出率,并与我们的分析结果表现出了极好的一致性。我们的工作表明,光滑的管是非差异扩散轨迹的替代物,并提供了一种直接的方法,可以将单个轨迹的理论结果(例如不可逆性的途径定义)与测量进行比较。

The trajectories of diffusion processes are continuous but non-differentiable, and each occurs with vanishing probability. This introduces a gap between theory, where path probabilities are used in many contexts, and experiment, where only events with non-zero probability are measurable. Here we bridge this gap by considering the probability of diffusive trajectories to remain within a tube of small but finite radius around a smooth path. This probability can be measured in experiment, via the rate at which trajectories exit the tube for the first time, thereby establishing a link between path probabilities and physical observables. Considering $N$-dimensional overdamped Langevin dynamics, we show that the tube probability can be obtained theoretically from the solution of the Fokker-Planck equation. Expressing the resulting exit rate as a functional of the path and ordering it as a power series in the tube radius, we identify the zeroth-order term as the Onsager-Machlup stochastic action, thereby elevating it from a mathematical construct to a physical observable. The higher-order terms reveal, for the first time, the form of the finite-radius contributions which account for fluctuations around the path. To demonstrate the experimental relevance of this action functional for tubes, we numerically sample trajectories of Brownian motion in a double-well potential, compute their exit rate, and show an excellent agreement with our analytical results. Our work shows that smooth tubes are surrogates for non-differentiable diffusive trajectories, and provide a direct way of comparing theoretical results on single trajectories, such as path-wise definitions of irreversibility, to measurement.

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