论文标题
硬玻璃材料的流变学
Rheology of Hard Glassy Materials
论文作者
论文摘要
玻璃状固体可能会在变形后发生流化(屈服)过渡,从而开始塑料流动。在不同的竞争放松/动力学过程中,是否由特定的时间尺度控制这个过程,这是一个争论的问题。在这里,在非抗弹性塑性性的微观模型中检查了两个组成模型的笼子弛豫模型。一个(广泛使用的)本构模型意味着总体松弛率是由结构($α$)放松率和剪切诱导的弛豫率之间最快的。这里是一个不同的模型,该模型假设最慢的(全局)放松过程控制整体放松。我们表明,第一个模型与存在有限的弹性剪切模量不兼容,用于绝对(低频)变形,而第二个模型能够描述“硬”玻璃固体变形的所有关键特征,包括屈服过渡,非承物到植入的高原交叉交叉和模量的速率。提出的框架提供了一种操作方法,可以根据结构放松时间的剪切率依赖性来区分“软”眼镜和“硬'玻璃杯”。
Glassy solids may undergo a fluidization (yielding) transition upon deformation whereby the material starts to flow plastically. It has been a matter of debate whether this process is controlled by a specific time scale, from among different competing relaxation/kinetic processes. Here, two constitutive models of cage relaxation are examined within the microscopic model of nonaffine elasto-plasticity. One (widely used) constitutive model implies that the overall relaxation rate is dominated by the fastest between the structural ($α$) relaxation rate and the shear-induced relaxation rate. A different model is formulated here which, instead, assumes that the slowest (global) relaxation process controls the overall relaxation. We show that the first model is not compatible with the existence of finite elastic shear modulus for quasistatic (low-frequency) deformation, while the second model is able to describe all key features of deformation of `hard' glassy solids, including the yielding transition, the nonaffine-to-affine plateau crossover, and the rate-stiffening of the modulus. The proposed framework provides an operational way to distinguish between `soft' glasses and `hard' glasses based on the shear-rate dependence of the structural relaxation time.