论文标题

几层rese $ _2 $的光学签名

The optical signature of few-layer ReSe$_2$

论文作者

Kipczak, Ł., Grzeszczyk, M., Olkowska-Pucko, K., Babiński, A., Molas, M. R.

论文摘要

展示了厚度从单(1 ml)到Nona-Layer(9 mls)的厚度,厚度为厚度(RESE $ _2 $)的薄层的光学性质。分别在低($ t $ = 5 K)和房间($ t $ = 300 K)温度下测量光致发光(PL)和拉曼散射。 RESE $ _2 $层的PL光谱显示两条良好的排放线,当层厚度从9 mLs降低到单层时,它们会蓝光约120 meV。可以在线性链模型中解释观察到的低能拉曼散射模式的丰富结构。在大约120 cm $^{ - 1} $下观察到的两种语体内振动的声子模式,表现出非常敏感和相反的进化,这是层厚度的函数。结果表明,他们的能量差可以作为方便且可靠的工具,以确定$ _2 $薄片的厚度在几层限制中。

Optical properties of thin layers of rhenium diselenide (ReSe$_2$) with thickness ranging from mono- (1 ML) to nona-layer (9 MLs) are demonstrated. The photoluminescence (PL) and Raman scattering were measured at low ($T$=5 K) and room ($T$=300 K) temperature, respectively. The PL spectra of ReSe$_2$ layers display two well-resolved emission lines, which blueshift by about 120 meV when the layer thickness decreases from 9 MLs to a monolayer. A rich structure of the observed low-energy Raman scattering modes can be explained within a linear chain model. The two phonon modes of intralayer vibrations, observed in Raman scattering spectra at about 120 cm$^{-1}$, exhibit very sensitive and opposite evolution as a function of layer thickness. It is shown that their energy difference can serve as a convenient and reliable tool to determine the thickness of ReSe$_2$ flakes in the few-layer limit.

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