论文标题
钻石的散装电子特性
Bulk electronic properties of diamond
论文作者
论文摘要
对绝缘,硼和磷的钻石的电子特性进行了回顾。主要目标是在更广泛的环境中显示数据,以揭示有关载体迁移率,电导率,P-和N型掺杂的趋势和局限性。未掺杂的钻石是在室温下电导率明显小于10^-17 ohmcm的绝缘体。通常,这些绝缘膜显示出1.7 eV的电导率激活能,这表明少量替代氮主要主导了费米级。电子和孔的迁移率很高(> 20.000 cm2/vs t = 80 K),受声音子散射的限制。磷和硼掺杂钻石的含量为600 MeV的N型供体激活能(磷)和370 MeV的受体激活能(Boron)。两种多巴德本质上都是氢状的。由于室温下的深层供体电导率有限,因此电子应用将是高温设备。电子和孔都显示出几乎相同的迁移率,这对于双极应用有希望,但是,由于掺杂水平截然不同,低温设备将由孔控制,而电子对更高温度的贡献的增加。温度对供体和受体的载体激活,载体散射以及通过跳跃运输的影响与某些基本的物理模型和描述结合了。结果证实了钻石的出色电子特性,这使得对将来的电子应用非常有希望。
A review of electronic properties of insulating-, boron- and phosphorus-doped diamond is given. The main goal is, to show data in a wider context, to reveal trends and limitations with respect to carrier mobilities, conductivities, p- and n-type doping. Undoped diamond is an insulator with conductivities significantly smaller than 10^-17 Ohmcm at room temperature. Mostly, these insulating films show conductivity activation energies of 1.7 eV, an indication that small amounts of substitutional nitrogen dominates the Fermi-level. The electron and hole mobilities are very high (> 20.000 cm2/Vs at T = 80 K) and are limited by acoustic phonon scattering. By phosphorus and boron doping diamond becomes semiconducting with an n-type donor activation energy (phosphorus) of 600 meV and an acceptor activation energy (boron) of 370 meV. Both dopands are hydrogen-like in nature. Due to the deep donor levels conductivity at room temperature is limited, electronic application will therefore be high-temperature devices. Both, electrons and holes show nearly the same mobilities which is promising for bi-polar applications, however, due to the very different doping levels low temperature devices will be governed by holes with increasing contribution of electrons towards higher temperatures. The effect of temperature on the carrier activation from donors and acceptors, on carrier scattering as well as on transport via hopping is shown in combination with some basic physical models and descriptions. The results confirm the superior electronic properties of diamond which makes it very promising for future electronic applications.