论文标题

状态的通用方程描述了整个凝胶过程的渗透压

Universal equation of state describes osmotic pressure throughout gelation process

论文作者

Yasuda, Takashi, Sakumichi, Naoyuki, Chung, Ung-il, Sakai, Takamasa

论文摘要

良好溶剂中线性聚合物溶液的渗透压状态方程是通过缩放函数普遍描述的。我们通过实验测量凝胶化过程的渗透压通过渗透渗透的压力。我们发现,线性聚合物溶液的相同缩放函数还描述了涉及溶胶和凝胶状态的整个胶凝过程的渗透压。此外,我们揭示了聚合物凝胶的渗透压普遍受线性聚合物溶液的半呈缩放定律的控制。

The equation of state of the osmotic pressure for linear-polymer solutions in good solvents is universally described by a scaling function. We experimentally measure the osmotic pressure of the gelation process via osmotic deswelling. We find that the same scaling function for linear-polymer solutions also describes the osmotic pressure throughout the gelation process involving both the sol and gel states. Furthermore, we reveal that the osmotic pressure of polymer gels is universally governed by the semidilute scaling law of linear-polymer solutions.

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