论文标题
Fe-葡萄糖酸盐的晶体结构
Crystal structures of Fe-gluconate
论文作者
论文摘要
Fe-葡萄糖酸Fe（C_6H_11O_1O_7_2XH_2O是一种广泛用于铁补充铁的知名材料。另一方面，它在食品行业中用作着色剂，在化妆品行业中用于皮肤和钉子条件和冶金。尽管在该研究中均未研究其物理性能的广泛范围。通过X射线衍射（XRD）研究了水合，0 <x <2（中间）和X = 0（干），Mössbauer光谱（MS）方法在20-300 K的温度范围内。对干燥的样品的p1是两种结构的校准。
Fe-gluconate, Fe(C_6H_11O_7_2xH_2O is a well-known material widely used for iron supplementation. On the other hand, it is used in food industry as a coloring agent, in cosmetic industry for skin and nail conditioning and metallurgy. Despite of wide range of applications its physical properties were not studied extensively. In this study, Fe-gluconate with three different amount of water viz. x=2 (fully hydrated, 0 < x < 2 (intermediate) and x=0 (dry) was investigated by means of X-ray diffraction (XRD) and Mössbauer spectroscopic (MS) methods. The former in the temperature range of 20-300 K, and the latter at 295 K. Based on the XRD measurements crystallographic structures were determined: monoclinic (space group I2) for the hydrated sample and triclinic (space group P1) for the dry sample. The partially hydrated sample was two-phased. Unit cells parameters for both structures show strong, very complex and non-monotonic temperature dependences. Mössbauer spectroscopic measurements gave evidence that iron in all samples exist in form of Fe(II) and Fe(III) ions. The amount of the latter equals to ca.30% in the hydrated sample and to ca.20% in the dry one.
