论文标题
用乙酸的Butan-1-Ol分子特性：一项介电研究
Molecular Properties of Butan-1-ol With Acetic Acid: A Dielectric study
论文作者
论文摘要
在反射模式下，在各种温度下（即288 K，298 K，308 K和318 K），在反射模式下，使用时域光谱在10 MHz至20 GHz的频率范围内研究了ButAN-1-OL与乙酸混合物的介电性能。已经确定了介电参数，例如静态介电常数和松弛时间。使用这些介电参数估算了过多的介电常数，过度的逆弛豫时间，柯克伍德相关因子和热力学参数（ΔH＆ΔS）。丁烷-1-ol与乙酸混合物的分子结构发生了巨大变化，这是由于复杂Sysytem分子之间的分子间相关性而观察到的。热力学参数探索了在不同温度下混合物的洞察分子结构的变化。
The dielectric properties of Butan-1-ol with acetic acid mixture have been studied in the frequency range 10 MHz to 20 GHz using time domain spectroscopy in the reflection mode, at various temperatures (i.e. on 288 K, 298 K, 308 K and 318 K) and at eleven different concentrations. Dielectric parameters such as static dielectric constant and relaxation time have been determined. Excess dielectric constant, Excess inverse relaxation time, Kirkwood correlation factor and the thermodynamic parameters (ΔH & ΔS) have been estimated using these dielectric parameters. A drastic change in molecular structure of Butan-1-ol with acetic acid mixture observed due to strong intermolecular association among the molecules of complex sysytem. Thermodynamic parameters explored to insight molecular structures changes of mixtures at different temperatures.
