论文标题
使用红外场对乙炔的严格非绝热量子控制
Strictly Non-Adiabatic Quantum Control of the Acetylene Dication Using an Infrared Field
论文作者
论文摘要
我们证明了在乙炔腐蚀性的去质子化中存在严格的非绝热控制途径。通过测量离子巧合实验中的动能转移来实验鉴定该途径。我们使用TDSE模拟来确定哪些属性最大程度地影响我们的控制。我们发现围绕圆锥形交叉点的谐振控制受到非绝热动力学速度的限制。
We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a TDSE simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics.
