论文标题

高压X射线吸收光谱研究的最新进展

Recent progress in high pressure X-ray absorption spectroscopy studies at the ODE beamline

论文作者

Nataf, L., Baudelet, F., Polian, A., Jonane, I., Anspoks, A., Kuzmin, A., Irifune, T.

论文摘要

高压能量分散性X射线吸收光谱是一种有价值的结构技术,尤其是与纳米聚晶型钻石小动脉细胞结合使用时。在这里,我们介绍了使用Soleil同步子处的Ode Beamine的色散设置获得的最新结果。在纳米晶CuO的示例中,讨论了压力和温度对X射线诱导的光量的影响。基于反向蒙特卡洛模拟,证明了在压力诱导的相变时遵循本地环境变化的可能性。

High pressure energy-dispersive X-ray absorption spectroscopy is a valuable structural technique, especially, when combined with a nano-polycrystalline diamond anvil cell. Here we present recent results obtained using the dispersive setup of the ODE beamline at SOLEIL synchrotron. The effect of pressure and temperature on the X-ray induced photoreduction is discussed on the example of nanocrystalline CuO. The possibility to follow local environment changes during pressure-induced phase transitions is demonstrated for alpha-MoO3 based on the reverse Monte Carlo simulations.

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